Here's the video from the August UpstatePHP meeting in Greenville discussing SQL vs NoSQL and where they are useful for your development process. I represented SQL solutions (*cough* PostgreSQL *cough*) while Benjamin Young represented NoSQL. Ben has actively contributed to CouchDB, worked for Cloudant, Couchbase, organizes the REST Fest Unconference (happening again September 25-27th) and is the owner of Big Blue Hat. I am a gainfully employed programmer...so...there's that.